Search results for " Pyrolysis"
showing 10 items of 49 documents
Occurrence of fossil organic matter in modern environments: optical, geochemical and isotopic evidence
2011
International audience; This study relates to the input and fate of fossil organic matter (FOM) in the modern environment, and focuses on two experimental watersheds overlying Jurassic marls: Le Laval and Le Brusquet (1 km(2) in area), located near Digne, Alpes-de-Haute-Provence, France. Considering that FOM delivery is mainly a result of different processes affecting sedimentary rocks [(bio)chemical and mechanical weathering], samples from different pools were collected: bedrocks, weathering profiles, soils and riverine particles. The samples were examined using complementary techniques: optical (palynofacies methods), geochemical (Rock-Eval 6 pyrolysis, C/N ratio), molecular (gas chromato…
Poplar Biochar as an Alternative Substrate for Curly Endive Cultivated in a Soilless System
2020
Imminent necessity for eco-friendly and low-cost substitutes to peat is a defiance in the soilless plant cultivation systems. Wood biochar could entirely or partly substitute peat as a plant growing constituent to produce vegetables. Nevertheless, knowledge concerning potential plant performance of leafy green vegetables grown on wood biochar is restricted. The present study assessed the main physicochemical traits of various growing media constituted by decreasing the content of peat and by increasing the percentages of poplar wood biochar. Yield, nutritional and functional properties of curly endive plants cultivated in a protected environment were also tested. Biochar was pyrolyzed from …
Analysis of optimal temperature, pressure and binder quantity for the production of biocarbon pellet to be used as a substitute for coke
2019
In order to contribute to the decarbonization of the economy, efficient alternatives to coal and coke should be found not only in the power sector but also in the industrial sectors (like steel, silicon and manganese production) in which coal and coke are used as a reductant and for steel production also as a fuel. To this aim many research works have been focused on the development of a coke substitute based on woody biomass and known as “biocarbon”. There are still barriers to overcome, among them: the biocarbon low density, poor mechanical strength and high reactivity. In this paper a new biocarbon production methodology is proposed, based on: pyrolysis at 600 °C, densification (using py…
Characterization of renewable reductants and charcoal-based pellets for the use in ferroalloy industries
2018
This study investigates the effect of high-temperature pyrolysis and post-treatment processes on spruce and oak charcoal yields and CO2 reactivity in a slow pyrolysis reactor. Post-treatment processes such as co-pyrolysis of biomass and recirculated tar mixture with that to the distillation of the charcoal-tar blend gave similar increase in charcoal yields. From a technological standpoint, co-pyrolysis of charcoal and tar mixture decreased the CO2 reactivity of the charcoal approaching that of fossil-based coke. This emphasize the importance of tar addition and high temperature treatment on charcoal properties. Moreover, the findings of this work show the potential use of the tar organic fr…
Assessment of bio-combustibles production via slow pyrolysis of wine industry residues
2018
With the aim of evaluating the potential production of high energy solid and liquid bio-fuels, a laboratory scale fixed bed reactor (FBR) derived from the standard Gray-King (GK) assay test on coal was used to carry out fixed bed pyrolysis experiments on wine industry by-products. The present study provides results on the pyrolysis of grape marc, residual from wine-making process, consisting of 50% by weight of grape seeds and 50% by weight of grape skins, at temperature between 150 and 500 °C, holding time of 30 minutes. Pyrolysis mass yields of solid (char) and liquid (tar) products and their corresponding energy properties, as a function of reaction temperature, are reported and discusse…
BIOCHAR SURFACE PROPERTIES THROUGH APPLICATION OF AN INNOVATIVE NMR TECHNIQUE: FAST FIELD CYCLING RELAXOMETRY
2013
Biochar is a carbonaceous material obtained by pyrolysis of biomass feedstocks. It is applied to soils in order to improve fertility and mitigate greenhouse-gases emissions. In fact, from the one hand, biochar changes physical-chemical soil properties, thereby affecting soil fertility. From the other hand, biochar is resistant to chemical and biochemical degradation. For this reason, its use allows carbon sequestration in soils and consequent reduction of carbon dioxide to the atmosphere. Here, dynamics of water at the liquid-solid interface of water saturated biochars is discussed. Results revealed that water dynamics is affected by the nature of biochar parent biomasses. Moreover, biochar…
Mechanisms of Organic Coating on the Surface of a Poplar Biochar
2017
Background: Recent studies highlighted that biochar efficiency to improve soil fertility is enhanced after it is blended with fresh organic materials. It was suggested that organic coating of inner-porous biochar surfaces acts as a kind of “glue” for plant-nutrients, thereby allowing their slow release towards plant-roots and/or microorganisms. Objective: The aim of the present study is to improve the understanding of the nature of the interactions between fresh organic matter and a poplar biochar. Method: Two fluorinated organic models were used as target molecules in order to apply heteronuclear (i.e. 19F) fast field cycling (FFC) NMR relaxometry. Results: The results suggest that organic…
Benzoxetes and Benzothietes ¾ Heterocyclic Analogues of Benzocyclobutene
2012
Benzo-condensed four-ring heterocycles, such as benzoxetes 1 and benzothietes 3 represent multi-purpose starting compounds for the preparation of various higher heterocyclic ring systems. The thermal or photochemical valence isomerizations between the benzenoid forms 1,3 and the higher reactive o-quinoid structures 2,4 provide the basis for the synthetic applications. On the other hand, this valence isomerization impedes in particular the generation and storage of 1 because the thermal equilibrium 1 ⇆ 2 is completely on the side of 2. Thus, the number of erroneous or questionable benzoxete structures published to date is surprisingly high. On the contrary, the thermal equilibrium 3 ⇆ 4 is o…
Preparation of photocatalysts by chemical methodologies
2021
Abstract The synthesis of photocatalytic materials is an important task for obtaining better results in terms of activity and/or selectivity in photocatalysis. This chapter reports an overview of the main methodologies using physical techniques to obtain bulky, supported powders or films and coatings to be used as heterogeneous photocatalysts. The classical chemical methodologies for the preparation of photocatalytic materials are presented in the previous chapter, so the information presented here complements the aforementioned one. Materials scientists and engineers have made significant progresses in the improvement of methods of synthesis of nanomaterial solids by developing different a…
The use of anthracene as a model compound in a comparative study of hydrous pyrolysis methods for industrial waste remediation
2011
Author's version of an article published in Chemosphere, 84 (4), 403-408. Also available from the publisher: http://dx.doi.org/10.1016/j.chemosphere.2011.03.061 Polycyclic aromatic hydrocarbons are very stable compounds and tend to bioaccumulate in the environment due to their high degree of conjugation and aromaticity. Hydrous pyrolysis is explored as a technique for the treatment of industrial water containing PAH, using anthracene as a model compound. The reactivity of anthracene under a range of temperatures and durations are studied in this paper. Aliquots of 1.0-10.0mg of anthracene in a range of 1.0-5.0 mL of H(2)O are subjected to hydrous pyrolysis under varied conditions of tempera…